Thermodynamic Properties of ThC-UC Solid Solutions

Cation distributions and thermodynamic properties of binary spinel solid solutions

A general model is presented to enable the calculation of the cation distribution and thermodynamic properties of any binary solid solution between oxide spinels containing 2*, 3* and 4* cations. The model includes the effect ofdisordering enthalpy which depends linearly on the degree of disorder. In addition there are important contributions to the thermodynamic properties from the size mismat...

Thermodynamic and magnetic properties of metastable FexCu100-x solid solutions formed by mechanical alloying

Metastable solid solutions of Fe and Cu, which are immiscible in equilibrium, have been formed using high-energy ball milling of elemental powder mixtures. Single-phase face-centered-cubic (fee) solid solution was obtained for 0 <x<60, and body-entered-cubic (bee) solid solution for 75(x < 100. The transition from fee to bee occurred near x=70, where a mixture of fee and bee phases was obtained...

Magnetic properties of FexCu100-x solid solutions.

Thermodynamic Properties of Solutions of Amino Acids and Related Substances

The effect of temperature on the thermodynamic ionization constants of compounds with dipole moments greater than those of the a-amino acids has not heretofore been studied. In this paper results are given for glycylglycine and c-aminocaproic acid, two substances with similar dipole moments. Measurements are also included for aspartic acid, which has recently been studied at 25” in cells withou...

An Evaluation of Four Electrolyte Models for the Prediction of Thermodynamic Properties of Aqueous Electrolyte Solutions

In this work, the performance of four electrolyte models for prediction the osmotic and activity coefficients of different aqueous salt solutions at 298 K, atmospheric pressure and in a wide range of concentrations are evaluated. In two of these models, (electrolyte Non-Random Two-Liquid e-NRTL and Mean Spherical Approximation-Non-Random Two-Liquid MSA-NRTL), association between ions of opposit...